COSMOSIL Index

COSMOSIL PBB-R

  • Pentabromobenzyl bonded stationary phase
  • Separation with dispersion force interaction
  • Distinguish various surfactants’ polyethylene glycol chain length
  • For separation of halogen exchange reaction products or aromatic compounds
Column Image

Column Specifications

Column Specifications

Applications

Halogen Exchange Reaction Products

COSMOSIL PBB-R strongly retains iodine atom which has a large dispersion force, than bromine atom. So it can separate halogen exchange reaction products that are difficult to analyze with C18 column.

halogen

Sample courtesy of Dr. H. Yamamoto, RIKEN

Condition
Column Size 4.6 mm I.D. x 150 mm halogen
Flow Rate 5PBB-R  Methanol : Water = 100 : 0
5C18-MS-II  Methanol : Water = 90 : 10
Temperature 30°C
Detection UV 254 nm
Sample Halogen exchange reaction products
Surfactant Agent

C18 column can not separate Triton X-100 mixturem, because (-OCH2CH2-) group has little hydrophobicity. However, COSMOSIL PBB-R can separate them because it distinguishes difference in the dispersion force, which depends on its molecular weight.

triton

Condition
Column Size 4.6 mm I.D. x 150 mm Triton X-100
Flow Rate 5PBB-R  Methanol : Water = 100 : 0
5C18-MS-II  Methanol : Water = 80 : 20
Temperature 30°C
Detection UV 254 nm
Sample Triton X-100
(5C18-MS-II  50 µg)
(5PBB-R      100 µg)

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Brochures

Ordering Information

Analytical Column (Particle Size : 5 µm)
COSMOSIL PBB-R
Product Name Size Product No.  Online
Catalog
COSMOSIL PBB-R Guard Column
4.6 mm I.D. x 10 mm 05704-11 e-Nacalai
10 mm I.D. x 20 mm 05721-81
20 mm I.D. x 20 mm 05911-91
20 mm I.D. x 50 mm 05722-71
COSMOSIL PBB-R Packed Column
1.0mm I.D. x 150 mm 05899-81 e-Nacalai
2.0 mm I.D. x 150 mm 05900-31
2.0 mm I.D. x 250 mm 05904-91
4.6 mm I.D. x 150 mm 05697-21
4.6 mm I.D. x 250 mm 05698-11
10 mm I.D. x 250 mm 05699-01
20 mm I.D. x 250 mm 05700-51

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